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Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil

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@article{IJASEIT10463,
   author = {Muhammad Said and Bobbie Rizkie Mandhala Hermanto and Muhammad Aidil Defitra and Febri Sandi and Risky Vernando},
   title = {Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil},
   journal = {International Journal on Advanced Science, Engineering and Information Technology},
   volume = {10},
   number = {1},
   year = {2020},
   pages = {374--380},
   keywords = {biolubricant; soybean oil; epoxidation; hydroxylation},
   abstract = {Biolubricant derived from vegetable oils is one of alternatives to substitute petroleum based lubricant. The biolubricant is environmental friendly, biodegradable, non toxic and renewable since it is derived from the vegetable oils. Soybean oil is potential as raw material for synthesis epoxide compound as intermediate substances for biolubricant since it has properties of high viscosity, low volatility, thermal stablity, vaporization stability and biodegradable. Polyol compound was produced through hydroxylation process of epoxide compound derived from the vegetable oils. The research aims to synthesize the epoxide compound from soybean oil, polyol compound synthesis from the epoxide compound and to determine kinetic reaction constants of the epoxidation and hydroxylation reactions. The process synthesis of the epoxide compound, as well as, polyol was carried out in a stirred glass reactors equipped with temperature measurement. The epoxidation reaction was carried out at 60 oC, 70 oC, and 80 oC with reaction time of 30 to 180 minutes with 30 minutes interval, while the hydroxylation reaction was carried out at 45 oC, 50 oC, 55 oC, and 60 oC with reaction time of 30 to 120 minutes with 30 minute interval. The highest conversion of soybean oil in epoxidation process was achieved 53.90 % at 70 oC and 120 minutes reaction time. The kinetic reaction constant for epoxidation reaction was achieved kep = 0.0046 min-1 at 70 oC. The highest conversion of hydroxylation process was achieved 91.52 % at 45 oC and 120 minutes reaction time. The kinetic reaction constant for hydroxylation reaction was achieved khd = 0.5528 min-1 at at 45 oC.},
   issn = {2088-5334},
   publisher = {INSIGHT - Indonesian Society for Knowledge and Human Development},
   url = {http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=10463},
   doi = {10.18517/ijaseit.10.1.10463}
}

EndNote

%A Said, Muhammad
%A Hermanto, Bobbie Rizkie Mandhala
%A Defitra, Muhammad Aidil
%A Sandi, Febri
%A Vernando, Risky
%D 2020
%T Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil
%B 2020
%9 biolubricant; soybean oil; epoxidation; hydroxylation
%! Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil
%K biolubricant; soybean oil; epoxidation; hydroxylation
%X Biolubricant derived from vegetable oils is one of alternatives to substitute petroleum based lubricant. The biolubricant is environmental friendly, biodegradable, non toxic and renewable since it is derived from the vegetable oils. Soybean oil is potential as raw material for synthesis epoxide compound as intermediate substances for biolubricant since it has properties of high viscosity, low volatility, thermal stablity, vaporization stability and biodegradable. Polyol compound was produced through hydroxylation process of epoxide compound derived from the vegetable oils. The research aims to synthesize the epoxide compound from soybean oil, polyol compound synthesis from the epoxide compound and to determine kinetic reaction constants of the epoxidation and hydroxylation reactions. The process synthesis of the epoxide compound, as well as, polyol was carried out in a stirred glass reactors equipped with temperature measurement. The epoxidation reaction was carried out at 60 oC, 70 oC, and 80 oC with reaction time of 30 to 180 minutes with 30 minutes interval, while the hydroxylation reaction was carried out at 45 oC, 50 oC, 55 oC, and 60 oC with reaction time of 30 to 120 minutes with 30 minute interval. The highest conversion of soybean oil in epoxidation process was achieved 53.90 % at 70 oC and 120 minutes reaction time. The kinetic reaction constant for epoxidation reaction was achieved kep = 0.0046 min-1 at 70 oC. The highest conversion of hydroxylation process was achieved 91.52 % at 45 oC and 120 minutes reaction time. The kinetic reaction constant for hydroxylation reaction was achieved khd = 0.5528 min-1 at at 45 oC.
%U http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=10463
%R doi:10.18517/ijaseit.10.1.10463
%J International Journal on Advanced Science, Engineering and Information Technology
%V 10
%N 1
%@ 2088-5334

IEEE

Muhammad Said,Bobbie Rizkie Mandhala Hermanto,Muhammad Aidil Defitra,Febri Sandi and Risky Vernando,"Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil," International Journal on Advanced Science, Engineering and Information Technology, vol. 10, no. 1, pp. 374-380, 2020. [Online]. Available: http://dx.doi.org/10.18517/ijaseit.10.1.10463.

RefMan/ProCite (RIS)

TY  - JOUR
AU  - Said, Muhammad
AU  - Hermanto, Bobbie Rizkie Mandhala
AU  - Defitra, Muhammad Aidil
AU  - Sandi, Febri
AU  - Vernando, Risky
PY  - 2020
TI  - Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil
JF  - International Journal on Advanced Science, Engineering and Information Technology; Vol. 10 (2020) No. 1
Y2  - 2020
SP  - 374
EP  - 380
SN  - 2088-5334
PB  - INSIGHT - Indonesian Society for Knowledge and Human Development
KW  - biolubricant; soybean oil; epoxidation; hydroxylation
N2  - Biolubricant derived from vegetable oils is one of alternatives to substitute petroleum based lubricant. The biolubricant is environmental friendly, biodegradable, non toxic and renewable since it is derived from the vegetable oils. Soybean oil is potential as raw material for synthesis epoxide compound as intermediate substances for biolubricant since it has properties of high viscosity, low volatility, thermal stablity, vaporization stability and biodegradable. Polyol compound was produced through hydroxylation process of epoxide compound derived from the vegetable oils. The research aims to synthesize the epoxide compound from soybean oil, polyol compound synthesis from the epoxide compound and to determine kinetic reaction constants of the epoxidation and hydroxylation reactions. The process synthesis of the epoxide compound, as well as, polyol was carried out in a stirred glass reactors equipped with temperature measurement. The epoxidation reaction was carried out at 60 oC, 70 oC, and 80 oC with reaction time of 30 to 180 minutes with 30 minutes interval, while the hydroxylation reaction was carried out at 45 oC, 50 oC, 55 oC, and 60 oC with reaction time of 30 to 120 minutes with 30 minute interval. The highest conversion of soybean oil in epoxidation process was achieved 53.90 % at 70 oC and 120 minutes reaction time. The kinetic reaction constant for epoxidation reaction was achieved kep = 0.0046 min-1 at 70 oC. The highest conversion of hydroxylation process was achieved 91.52 % at 45 oC and 120 minutes reaction time. The kinetic reaction constant for hydroxylation reaction was achieved khd = 0.5528 min-1 at at 45 oC.
UR  - http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=10463
DO  - 10.18517/ijaseit.10.1.10463

RefWorks

RT Journal Article
ID 10463
A1 Said, Muhammad
A1 Hermanto, Bobbie Rizkie Mandhala
A1 Defitra, Muhammad Aidil
A1 Sandi, Febri
A1 Vernando, Risky
T1 Synthesis of Epoxide and Polyol Compounds as Intermediates for Biolubricant from Soybean Oil
JF International Journal on Advanced Science, Engineering and Information Technology
VO 10
IS 1
YR 2020
SP 374
OP 380
SN 2088-5334
PB INSIGHT - Indonesian Society for Knowledge and Human Development
K1 biolubricant; soybean oil; epoxidation; hydroxylation
AB Biolubricant derived from vegetable oils is one of alternatives to substitute petroleum based lubricant. The biolubricant is environmental friendly, biodegradable, non toxic and renewable since it is derived from the vegetable oils. Soybean oil is potential as raw material for synthesis epoxide compound as intermediate substances for biolubricant since it has properties of high viscosity, low volatility, thermal stablity, vaporization stability and biodegradable. Polyol compound was produced through hydroxylation process of epoxide compound derived from the vegetable oils. The research aims to synthesize the epoxide compound from soybean oil, polyol compound synthesis from the epoxide compound and to determine kinetic reaction constants of the epoxidation and hydroxylation reactions. The process synthesis of the epoxide compound, as well as, polyol was carried out in a stirred glass reactors equipped with temperature measurement. The epoxidation reaction was carried out at 60 oC, 70 oC, and 80 oC with reaction time of 30 to 180 minutes with 30 minutes interval, while the hydroxylation reaction was carried out at 45 oC, 50 oC, 55 oC, and 60 oC with reaction time of 30 to 120 minutes with 30 minute interval. The highest conversion of soybean oil in epoxidation process was achieved 53.90 % at 70 oC and 120 minutes reaction time. The kinetic reaction constant for epoxidation reaction was achieved kep = 0.0046 min-1 at 70 oC. The highest conversion of hydroxylation process was achieved 91.52 % at 45 oC and 120 minutes reaction time. The kinetic reaction constant for hydroxylation reaction was achieved khd = 0.5528 min-1 at at 45 oC.
LK http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=10463
DO  - 10.18517/ijaseit.10.1.10463