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Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis

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@article{IJASEIT2427,
   author = {Iryanti Fatyasari Nata and Meilana Dharma Putra and Desi Nurandini and Chairul Irawan},
   title = {Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis},
   journal = {International Journal on Advanced Science, Engineering and Information Technology},
   volume = {7},
   number = {4},
   year = {2017},
   pages = {1302--1308},
   keywords = {C-SO3H;  sulphonated; biocarbon; glucose; hydrolysis; banana peel starch},
   abstract = {The sulphonated biocarbon (C-SO3H) has been prepared from carbonization of corn cob and followed by one-step hydrothermal treatment. This research focus on characterization of C-SO3H and evaluate the capability of C-SO3H for hydrolyzed banana peel starch, and also investigate the optimum concentrations of substrate and the reaction time for hydrolysis. The C-SO3H was produced from corn cob (±60 mm mesh); it was carbonized at 400 °C for 1 hour. The resulting carbon was sulphonated by hydroxy ethyl sulphonic acid at 180 °C for 4 hours, and then washed with 50% methanol and water, and then resulting biocarbon was dried at 80 °C for 6 hour in oven. Based on Scanning Electron Microscopy (SEM) observation, structure morphology of corn cob was changed due to carbonization process. The C-SO3H after sulphonation has random pores with diameter around 3 µm–10 µm. The X-Ray Diffraction (XRD) showed increased of crystalline index of corn cob about 133% after carbonization. Analysis of EDX result for S component on C-SO3H is 3.79% w/w and capacity of H+ is 1.447 mmol/g. The apparent peaks of -SO3H functional groups (1207 cm-1 and 1720 cm-1) on C-SO3H were indicated the by Fourier Transform Infra Red (FTIR). Optimum hydrolysis concentration of banana peel starch is 7% w/v for 60 min at 100oC which Total Reducing Sugar (TRS) concentration about 0.688 mg/mL. Reusability of C-SO3H for 4 repeated used which showed a good performance that only 6% of decreasing activity of C-SO3H. The utilization of corn cob can be enhanced of corn cob and also it can be utilized as heterogeneous catalyst.},
   issn = {2088-5334},
   publisher = {INSIGHT - Indonesian Society for Knowledge and Human Development},
   url = {http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=2427},
   doi = {10.18517/ijaseit.7.4.2427}
}

EndNote

%A Nata, Iryanti Fatyasari
%A Putra, Meilana Dharma
%A Nurandini, Desi
%A Irawan, Chairul
%D 2017
%T Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis
%B 2017
%9 C-SO3H;  sulphonated; biocarbon; glucose; hydrolysis; banana peel starch
%! Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis
%K C-SO3H;  sulphonated; biocarbon; glucose; hydrolysis; banana peel starch
%X The sulphonated biocarbon (C-SO3H) has been prepared from carbonization of corn cob and followed by one-step hydrothermal treatment. This research focus on characterization of C-SO3H and evaluate the capability of C-SO3H for hydrolyzed banana peel starch, and also investigate the optimum concentrations of substrate and the reaction time for hydrolysis. The C-SO3H was produced from corn cob (±60 mm mesh); it was carbonized at 400 °C for 1 hour. The resulting carbon was sulphonated by hydroxy ethyl sulphonic acid at 180 °C for 4 hours, and then washed with 50% methanol and water, and then resulting biocarbon was dried at 80 °C for 6 hour in oven. Based on Scanning Electron Microscopy (SEM) observation, structure morphology of corn cob was changed due to carbonization process. The C-SO3H after sulphonation has random pores with diameter around 3 µm–10 µm. The X-Ray Diffraction (XRD) showed increased of crystalline index of corn cob about 133% after carbonization. Analysis of EDX result for S component on C-SO3H is 3.79% w/w and capacity of H+ is 1.447 mmol/g. The apparent peaks of -SO3H functional groups (1207 cm-1 and 1720 cm-1) on C-SO3H were indicated the by Fourier Transform Infra Red (FTIR). Optimum hydrolysis concentration of banana peel starch is 7% w/v for 60 min at 100oC which Total Reducing Sugar (TRS) concentration about 0.688 mg/mL. Reusability of C-SO3H for 4 repeated used which showed a good performance that only 6% of decreasing activity of C-SO3H. The utilization of corn cob can be enhanced of corn cob and also it can be utilized as heterogeneous catalyst.
%U http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=2427
%R doi:10.18517/ijaseit.7.4.2427
%J International Journal on Advanced Science, Engineering and Information Technology
%V 7
%N 4
%@ 2088-5334

IEEE

Iryanti Fatyasari Nata,Meilana Dharma Putra,Desi Nurandini and Chairul Irawan,"Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis," International Journal on Advanced Science, Engineering and Information Technology, vol. 7, no. 4, pp. 1302-1308, 2017. [Online]. Available: http://dx.doi.org/10.18517/ijaseit.7.4.2427.

RefMan/ProCite (RIS)

TY  - JOUR
AU  - Nata, Iryanti Fatyasari
AU  - Putra, Meilana Dharma
AU  - Nurandini, Desi
AU  - Irawan, Chairul
PY  - 2017
TI  - Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis
JF  - International Journal on Advanced Science, Engineering and Information Technology; Vol. 7 (2017) No. 4
Y2  - 2017
SP  - 1302
EP  - 1308
SN  - 2088-5334
PB  - INSIGHT - Indonesian Society for Knowledge and Human Development
KW  - C-SO3H;  sulphonated; biocarbon; glucose; hydrolysis; banana peel starch
N2  - The sulphonated biocarbon (C-SO3H) has been prepared from carbonization of corn cob and followed by one-step hydrothermal treatment. This research focus on characterization of C-SO3H and evaluate the capability of C-SO3H for hydrolyzed banana peel starch, and also investigate the optimum concentrations of substrate and the reaction time for hydrolysis. The C-SO3H was produced from corn cob (±60 mm mesh); it was carbonized at 400 °C for 1 hour. The resulting carbon was sulphonated by hydroxy ethyl sulphonic acid at 180 °C for 4 hours, and then washed with 50% methanol and water, and then resulting biocarbon was dried at 80 °C for 6 hour in oven. Based on Scanning Electron Microscopy (SEM) observation, structure morphology of corn cob was changed due to carbonization process. The C-SO3H after sulphonation has random pores with diameter around 3 µm–10 µm. The X-Ray Diffraction (XRD) showed increased of crystalline index of corn cob about 133% after carbonization. Analysis of EDX result for S component on C-SO3H is 3.79% w/w and capacity of H+ is 1.447 mmol/g. The apparent peaks of -SO3H functional groups (1207 cm-1 and 1720 cm-1) on C-SO3H were indicated the by Fourier Transform Infra Red (FTIR). Optimum hydrolysis concentration of banana peel starch is 7% w/v for 60 min at 100oC which Total Reducing Sugar (TRS) concentration about 0.688 mg/mL. Reusability of C-SO3H for 4 repeated used which showed a good performance that only 6% of decreasing activity of C-SO3H. The utilization of corn cob can be enhanced of corn cob and also it can be utilized as heterogeneous catalyst.
UR  - http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=2427
DO  - 10.18517/ijaseit.7.4.2427

RefWorks

RT Journal Article
ID 2427
A1 Nata, Iryanti Fatyasari
A1 Putra, Meilana Dharma
A1 Nurandini, Desi
A1 Irawan, Chairul
T1 Facile Strategy for Surface Functionalization of Corn Cob to Biocarbon and Its Catalytic Performance on Banana Peel Starch Hydrolysis
JF International Journal on Advanced Science, Engineering and Information Technology
VO 7
IS 4
YR 2017
SP 1302
OP 1308
SN 2088-5334
PB INSIGHT - Indonesian Society for Knowledge and Human Development
K1 C-SO3H;  sulphonated; biocarbon; glucose; hydrolysis; banana peel starch
AB The sulphonated biocarbon (C-SO3H) has been prepared from carbonization of corn cob and followed by one-step hydrothermal treatment. This research focus on characterization of C-SO3H and evaluate the capability of C-SO3H for hydrolyzed banana peel starch, and also investigate the optimum concentrations of substrate and the reaction time for hydrolysis. The C-SO3H was produced from corn cob (±60 mm mesh); it was carbonized at 400 °C for 1 hour. The resulting carbon was sulphonated by hydroxy ethyl sulphonic acid at 180 °C for 4 hours, and then washed with 50% methanol and water, and then resulting biocarbon was dried at 80 °C for 6 hour in oven. Based on Scanning Electron Microscopy (SEM) observation, structure morphology of corn cob was changed due to carbonization process. The C-SO3H after sulphonation has random pores with diameter around 3 µm–10 µm. The X-Ray Diffraction (XRD) showed increased of crystalline index of corn cob about 133% after carbonization. Analysis of EDX result for S component on C-SO3H is 3.79% w/w and capacity of H+ is 1.447 mmol/g. The apparent peaks of -SO3H functional groups (1207 cm-1 and 1720 cm-1) on C-SO3H were indicated the by Fourier Transform Infra Red (FTIR). Optimum hydrolysis concentration of banana peel starch is 7% w/v for 60 min at 100oC which Total Reducing Sugar (TRS) concentration about 0.688 mg/mL. Reusability of C-SO3H for 4 repeated used which showed a good performance that only 6% of decreasing activity of C-SO3H. The utilization of corn cob can be enhanced of corn cob and also it can be utilized as heterogeneous catalyst.
LK http://ijaseit.insightsociety.org/index.php?option=com_content&view=article&id=9&Itemid=1&article_id=2427
DO  - 10.18517/ijaseit.7.4.2427