Performance of Cement Mortar Containing Micro and Ultrafine Metakaolin Binders

Steve W.M Supit (1), Rilya Rumbayan (2), Adriana Ticoalu (3)
(1) Department of Civil Engineering, Manado State Polytechnic, Manado, 95252, Indonesia
(2) Department of Civil Engineering, Manado State Polytechnic, Manado, 95252, Indonesia
(3) Sam Ratulangi University, Jl. Kampus Bahu, Manado, 95115, Indonesia
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Supit, Steve W.M, et al. “Performance of Cement Mortar Containing Micro and Ultrafine Metakaolin Binders”. International Journal on Advanced Science, Engineering and Information Technology, vol. 12, no. 1, Jan. 2022, pp. 306-12, doi:10.18517/ijaseit.12.1.9333.
Research into the usage of locally available construction material is essential and beneficial in ensuring a cost-effective construction project. One of the natural resources that be used as supplementary cementitious material is metakaolin. This research aims to investigate the performance of mortar reinforced with micro- and ultrafine metakaolin based on compressive strength and water absorption tests. Locally sourced metakaolin was mixed in cement mortar after calcined at 800ï‚°C with a variation amount of 0%, 5%, and 10% by wt. The tests were conducted on the 50mmx50mmx50mm cube specimens after water curing at 7 and 28 days, following the ASTM-standards. Results show that specimens containing 10% of micro- and ultrafine-metakaolin (MK-10 and UM-10) exhibited the highest compressive strength and better water-resistance characteristics when compared to control mortar. In this case, the addition of 10% ultrafine metakaolin (UM-10) reached the highest compressive strength value with approximately 121% and 100% higher than the compressive strength of control mortar on the 7th and 28th day, respectively. Additionally, the water absorption of UM-10 at 28 days was found to be 86% and 30% lower than PCC and MK-10, respectively. Furthermore, X-Ray Diffraction (XRD) and Thermogravimetric graphs of pastes with micro- and ultrafine-metakaolin indicate a reduction of CH; therefore, the production of more CSH gel. The densification of cement paste with ultrafine-metakaolin is also confirmed by nitrogen adsorption analysis indicating ultrafine-metakaolin's inert filler effect in forming a denser matrix.

Tunega, D, and Zaoui, A., “Mechanical and bonding behaviors behind the bending mechanism of kaolinite clay”, J. Phys. Chemical. C, 124, 13, pp. 7432-7440, 2020.

Guatame-Garcia, A., Buxton, M., Deon, F, Lievens, C., and Hecker, C. “Toward an on-line characterisation of kaolin calcination process using short-wave infrared spectroscopy), Mineral Processing and Extractive Metallurgy Review, 39:6, pp, 420-432, 2018.

Abo-El-Enein, S.A, et al., “Pozzolanic and hydraulic activity of ultrafine-metakaolin”, HBRC Journal, Elsevier, 10(1), 2014, pp. 64-72.

ASTM C618 - 15, “Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete”, ASTM International, 2015.

Vu, D. D., “Strength properties of metakaolin-blended paste, mortar and concrete”. PhD Thesis, DUP Science, Delft University Press, The Netherlands, 2002.

Supit, S., Rumbayan, R., and Ticoalu, A., “A Study on the effects of metakaolin from Toraget Village in Indonesia”, on Cement Concrete Properties, IASTEM Journal, 2016.

Narmatha, M., Felixkala, T., “Metakaolin-the best material for replacement of cement in concrete”, IOSR Journal of Mechanical and Civil Engineering, Vol. 13, Issue 4 Ver 1, pp.66-71, 2016.

Sayamipuk, S., “Development of durable mortar and concrete incorporating Metakaolin in Thailand”, Doctoral dissertation No. ST-00-1, Asian Institute of Technology, Bangkok, 2000.

Batis, G., et al., “The effect of Metakaolin on the corrosion behavior of cement mortars”, Cement and Concrete Composites, Elsevier, 27, 2004, pp. 125-130.

Thankam, G, L., and Renganathan, T. “Ideal supplementary cementing material-Metakaolin: A review. International Review of Applied Sciences and Engineering, Vol. 11: Issue 1, https://doi.org/10.1556/1848.2020.00008, 2020.

Supit, S., Rumbayan, R., and Ticoalu, A., “Effects of nano-metakaolin on cement mortar and concrete properties”, 2nd International RILEM/COST Conference on Early Age Cracking and Serviceability in Cement-based Materials and Structures, Belgium, 12-14 September 2017.

Duan P, et al., “Effects of metakaolin, silica fume and slag on pore structure, interfacial transition zone and compressive strength of concrete”, Construction and Building Materials, 44, 2013.

Sobolev, K., Flores, I., Hermosillo, R., and Torres-Martines, L., (2006) “Nanomaterials and nanotechnology for high performance cement composites”. Proceedings of ACI Session on “Nanotechnology of concrete: Recent developments and future perspectives”, November 7, 2006, USA.

Supit, W.M.S., Rumbayan, R., and Ticoalu, A., “Mechanical properties of cement concrete composites containing ultrafine-metakaolin”. AIP Conference Proceedings, 1903, 050001, 2017.

ASTM C230/C230M-14, “Standard Test Method for Flow Table for Use in Tests of Hydraulic Cement”, ASTM International, 2014.

ASTM C1437-15, “Standard Test Method for Flow of Hydraulic Cement Mortar”, ASTM International, 2015.

ASTM C109/C109M-02, “Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens)”, ASTM International, 2002.

ASTM C1403-15, “Standard Test Method for Rate of Water Absorption of Masonry Mortars”, ASTM International, 2015.

Ling, G et al., “Rheological behaviour and microstructure characteristics of SCC incorporating metakaolin and silica fume”. Materuals (Basel), 11(12), 2576, doi: 10.3390/ma11122576, 2018.

Chen, J., Li, W., Li, L., and Kwan, A, “Cement equivalence of metakaolin for workability, cohesiveness strength and sorptivity of concrete. Materials (Basel), 13(7), 1646, doi: 10.3390/ma13071646, 2020.

Fan, Y, Zhang, S, Kawashima, S, Shah, S., “Influence of kaolinite clay on the chloride diffusion property of cement-based materials”. Cement and Concrete Composites, Vol. 45, pp. 117-124., 2014.

Sithara, A, and Daniel, S.A. “Comparative study of nano fly ash concrete and nano metakaolin concrete with normal cement concrete”. International Journal of Engineering Science Invention Research and Development, Vol. III, Issue III, ISSN:2349-6185, 2016.

Morsy, M, Mokhtar, M, Shoukry, H, El-Khodary, S. “Facile production of nano-scale metakaolin: An investigation into its effect on compressive strength, pore structure and microstructural characteristics of mortar”. Construction and Building Materials¸Vol. 172, pp. 243-250, 2018.

Fadzil, M.A, Norhasri, M, Hamidah, M, Zaidi, M, Faizal, M. “Alteration of nano metakaolin for ultra-high performance concrete (UHPC)”. International Civil and Infrastructure Engineering Conference, September 22-24, Kuching, Malaysia, 2013.

Al-Salami, A.E, and Al-Gawati, M.A. (2013). “Pozzolanic activity of nano-silica and its application for improving physical, mechanical and structural properties of hardened cement”. International Journal of Applied Physics and Mathematics, Vol. 3, No.6, November 2013.

El-Diadamony, H, Amer, A.A, Sokkary, T.M, and El-Hoseny,S. “Hydration and characteristics of metakaolin pozzolanic cement pastes”. HBRC Journal, https://doi.org/10.1016/j.hbrcj.2015.05.005, 2016.

Mliní¡rik, L, and Kopecskó, K., “Impact of metakaolin - a new supplementary material on the hydration mechanism of cements”, Acta Technica Napocensis: Civil Engineering and Architecture, 56(2), 2013.

Puerta-Falla, G, Balonis, M, Saout, G.L, Neithalath, N, and Sant, G. “The influence of metakaolin on limestone reactivity in cementitious materials” in RILEM Bookseries 10, Calcined Clays for Sustainable Concrete (K. Scrivener and A. Favier (eds), DOI 10.1007/978-94-017-9939-3-2, 2015.

Wang, X. “Effects of nanoparticles on the properties of cement-based materials”. Graduate Theses and Dissertations, Iowa State University, 2017.

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